OPTIMIZATION OF FLUORIDE-ION CONDUCTION IN NEW FLUORITE-TYPE ANION EXCESS SOLID-SOLUTIONS INVOLVING 2 SUBSTITUTIONAL CATIONS

被引：10

作者：

WAHBI, M ^{[1
]}

REAU, JM ^{[1
]}

SENEGAS, J ^{[1
]}

HAGENMULLER, P ^{[1
]}

机构：

[1] UNIV BORDEAUX 1,CNRS,CHIM SOLIDE LAB,351 COURS LIBERAT,F-33405 TALENCE,FRANCE

来源：

SOLID STATE IONICS | 1993年 / 59卷 / 1-2期

关键词：

D O I：

10.1016/0167-2738(93)90233-S

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

New fluorite-type anion excess phases have been prepared within the PbF2-M'F3-ZrF4 (M' = In, Bi) systems involving simultaneously trivalent and tetravalent cations. The materials showing the highest ionic conductivity are characterized by presence of column clusters of (n = 2) size and by values of the Zr/In and Bi/Zr ratios close to 1/2. The obtained results are discussed on the base of a previously set up clustering model.

引用

页码：83 / 92

页数：10

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