SYNTHESIS AND STRUCTURE OF LI3RHH6 - A TERNARY HYDRIDE WITH ISOLATED [RHH6](3-) OCTAHEDRA

被引：13

作者：

BRONGER, W

GEHLEN, M

AUFFERMANN, G

机构：

[1] Institut für Anorganische Chemie, Technischen Hochschule Aachen, Aachen, D‐52056

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1994年 / 620卷 / 11期

关键词：

METAL HYDRIDES; RHODIUM; LITHIUM; CRYSTAL STRUCTURE; NEUTRON DIFFRACTION;

D O I：

10.1002/zaac.19946201124

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The ternary rhodium hydride Li3RhH6 was synthesized by the reaction of lithium hydride with rhodium under a hydrogen pressure of 80 bar. X-ray investigations on powdered samples and an elastic neutron diffraction experiment on the deuterated compound led to the complete structure determination (space group: Pnma, Z = 4). The atomic arrangement is isotypic to the Na3RhH6 structure type. The crystal structure contains isolated [RhH6](3-) octahedra, which are separated by the lithium ions.

引用

页码：1983 / 1985

页数：3

共 13 条

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[2] SYNTHESIS AND STRUCTURE OF LI3RHH4, A TERNARY HYDRIDE WITH PLANAR [RHH4]3- GROUPS
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[7] SYNTHESIS AND STRUCTURE OF RB3PDH3 AND RB3PDH5
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[8] SYNTHESIS, STRUCTURE AND PHASE-TRANSITION OF RB2PDH4 AND CS2PDH4
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[9] SYNTHESIS AND STRUCTURE OF TERNARY PALLADIUM HYDRIDES A3PDH5 WHERE A = K, RB AND CS
BRONGER, W
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[10] NA3RHH6, NA3IRH6 AND LI3IRH6, NEW COMPLEX HYDRIDES WITH ISOLATED [RHH6](3-)-OCTAHEDRA AND [IRH6](3-)-OCTAHEDRA
BRONGER, W
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AUFFERMANN, G
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