共 13 条
- [11] BRONGER W, 1994, ANGEW CHEM, V106, P1144
- [12] BRONGER W, 1992, INT S METAL HYDROG 2, P42
- [13] HALL SR, 1989, XTAL 2 6 USERS MANUA
SYNTHESIS AND STRUCTURE OF LI3RHH6 - A TERNARY HYDRIDE WITH ISOLATED [RHH6](3-) OCTAHEDRA
被引：13
作者：
BRONGER, W
GEHLEN, M
AUFFERMANN, G
机构：
[1] Institut für Anorganische Chemie, Technischen Hochschule Aachen, Aachen, D‐52056
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
|
1994年
/
620卷
/
11期
关键词：
METAL HYDRIDES;
RHODIUM;
LITHIUM;
CRYSTAL STRUCTURE;
NEUTRON DIFFRACTION;
D O I：
10.1002/zaac.19946201124
中图分类号：
O61 [无机化学];
学科分类号：
070301 ;
081704 ;
摘要：
The ternary rhodium hydride Li3RhH6 was synthesized by the reaction of lithium hydride with rhodium under a hydrogen pressure of 80 bar. X-ray investigations on powdered samples and an elastic neutron diffraction experiment on the deuterated compound led to the complete structure determination (space group: Pnma, Z = 4). The atomic arrangement is isotypic to the Na3RhH6 structure type. The crystal structure contains isolated [RhH6](3-) octahedra, which are separated by the lithium ions.
引用
收藏
页码：1983 / 1985
页数：3
相关论文