SYNTHESIS AND CHARACTERIZATION OF IRON CLATHROCHELATE COMPLEXES DERIVED FROM OXIME HYDRAZONE LIGANDS AND CAPPED BY FERROCENYLBORATE AND 1,1'-FERROCENEDIYLDIBORATE

被引：20

作者：

BIEDA, KL ^{[1
]}

KRANITZ, AL ^{[1
]}

GRZYBOWSKI, JJ ^{[1
]}

机构：

[1] GETTYSBURG COLL, DEPT CHEM, GETTYSBURG, PA 17325 USA

来源：

INORGANIC CHEMISTRY | 1993年 / 32卷 / 20期

关键词：

D O I：

10.1021/ic00072a010

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis and characterization of a series of iron clathrochelate complexes based on oxime-hydrazone ligands and capped with ferrocenylboronic acid to produce dimetallic species is reported. The first example of a metal complex which uses 1,1'-ferrocenediyldiboronic acid as a capping/bridging agent between two clathrochelate complexes to form a novel trimetallic species is also presented. The redox chemistry of these multiple metal systems is examined by cyclic voltammetry and controlled-potential electrolysis. The generation of stable mixed-valent (Fe2+/Fe3+) species by exhaustive electrolysis and their subsequent characterization by UV-visible spectroscopy and cyclic voltammetry is discussed.

引用

页码：4209 / 4213

页数：5

共 29 条

[21] SYNTHESIS AND OXIDATION OF 2 FERROCENE-CAPPED COBALT CLATHROCHELATES IN METHYLENE-CHLORIDE [J].