HINDERED ROTATION AT THE TRIPLE BOND

被引：21

作者：

MEW, PKT ^{[1
]}

VOGTLE, F ^{[1
]}

机构：

[1] UNIV BONN,INST ORGAN CHEM & BIOCHEM,D-5300 BONN 1,FED REP GER

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1979年 / 18卷 / 02期

关键词：

D O I：

10.1002/anie.197901591

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Rotation within the linear (Figure Presented.) group can be hindered by substituents; the first example is bis(dimethyltriptycenyl)ethyne 1, RiRaCH3. Stuart‐Briegleb space‐filling models do not reproduce this effect. (Figure Presented.) Copyright © 1979 by Verlag Chemie, GmbH, Germany

引用

页码：159 / 161

页数：3

共 12 条

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[7] HINDERED ROTATION AROUND C(9)-CH2CL BONDS IN CHLOROMETHYLTRIPTYCENES
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SKVARCHE.VR
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[8] Shanan-Atidi H., 1970, Journal of Physical Chemistry, V74, P961, DOI 10.1021/j100699a054
[9] C-C BOND FORMATION BY SULFONE PYROLYSIS .13. TRIPTYCENOPHANES - SYNTHESIS VIA DOUBLE NON-BENZYLIC SULFONE PYROLYSIS
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[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1978, 17 (01): : 60 - 62
[10] VOGTLE F, 1977, ANGEW CHEM INT EDIT, V16, P429

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