STRUCTURAL EVIDENCE OF THE AROMATICITY OF BOREPINS - A COMPARISON OF 1-CHLOROBOREPIN AND TRICARBONYL(1-CHLOROBOREPIN)MOLYBDENUM

被引：30

作者：

ASHE, AJ

KAMPF, JW

KLEIN, W

ROUSSEAU, R

机构：

[1] Department of Chemistry, University of Michigan, Ann Arbor, Michigan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 07期

关键词：

D O I：

10.1002/anie.199310651

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A planar structure with C2v symmetry is a description of 1-chloroborepin 1, and is consistent with the presumption that 1 and probably also 1H-borepin are aromatic compounds. The Mo(CO)3 complex was prepared from 1. Its structure was also determined, and it could be reduced to the stable complex 2.

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页码：1065 / 1066

页数：2

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