IONIC-CONDUCTIVITY AND BATTERY CHARACTERISTIC STUDIES ON PEO+AGNO3 POLYMER ELECTROLYTE

被引:63
作者
RAO, SS [1 ]
RAO, KVS [1 ]
SHAREEFUDDIN, M [1 ]
RAO, UVS [1 ]
CHANDRA, S [1 ]
机构
[1] BHU,DEPT PHYS,VARANASI 221005,INDIA
关键词
D O I
10.1016/0167-2738(94)90026-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A new Ag+ ion conducting polymer electrolyte based on PEO+AgNO3 system is reported. The solvation of Ag+ ion with PEO is confirmed by XRD studies. The electrical conductivity and cell discharge characteristics at room temperature (32-degrees-C) are reported. The highest conductivity (9.2 X 10-3 S Cm-1) has been observed for 80:20 composition (i.e. Ag+/E0=0.6). An electrochemical cell with the configuration Ag/PEO + AgNO3/(I2 + C + electrolyte) has also been studied [ for which open circuit voltage (OCV) = 610 mV and short circuit current (SCC) = 4.4. X 10(-6) A] and a number of cell parameters obtained are reported.
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页码:331 / 334
页数:4
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