Intramolecular formation of p-methylbenzyl radical from p-xylene

被引:13
作者
Johnson, Philip M.
Rice, Stuart A.
机构
[1] Univ Chicago, Dept Chem, Chicago, IL 60637 USA
[2] Univ Chicago, James Franck Inst, Chicago, IL 60637 USA
关键词
D O I
10.1016/0009-2614(68)80128-9
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In order to show that the dissociation of a methyl hydrogen atom from a methylbenzene by light is an intramolecular process, p-xylene was prepared in a solid argon matrix. Irradiation of this solution in the near ultraviolet produced the known radical emission.
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页码:709 / 711
页数:3
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