DUAL AND INCIDENT CIRCULAR-POLARIZATION RAMAN OPTICAL-ACTIVITY BACKSCATTERING OF (-)-TRANS-PINANE

被引:52
作者
CHE, DP
HECHT, L
NAFIE, LA
机构
[1] Department of Chemistry, Syracuse University, Syracuse
基金
美国国家卫生研究院;
关键词
D O I
10.1016/0009-2614(91)87138-2
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
We report the first measurement of dual circular polarization (DCP) Raman optical activity (ROA). DCP ROA was predicted recently to be a new form of ROA in which the incident and scattered light beams are synchronously modulated between right and left circular polarization states. Using a new backscattering apparatus and ( - )-trans-pinane, we confirm the theoretical predictions and compare our results to the conventional incident circular polarization (ICP) form of ROA.
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页码:182 / 190
页数:9
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