THE 1ST ORGANOSELENIUM ATE COMPLEX

被引：21

作者：

REICH, HJ

GUDMUNDSSON, BO

DYKSTRA, RR

机构：

[1] Department of Chemistry, University of Wisconsin, Madison

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1992年 / 114卷 / 20期

关键词：

D O I：

10.1021/ja00046a064

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The enormous rate acceleration of the intramolecular Li/S exchange 3-S/3′-S and the unusual stability of the selenium ate complex 4-Se suggest that the structure of 4 is close to the ideal geometry of such ate complexes, and provides support for the intermediacy of ate complexes in Li/S and Li/Se exchanges. © 1992, American Chemical Society. All rights reserved.

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页码：7937 / 7938

页数：2

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