ELECTROCHEMICAL EPOXIDATION OF ELECTRON-POOR OLEFINS USING SILVER BIPYRIDINE BASED REDOX MEDIATORS

被引：6

作者：

KANDZIA, C ^{[1
]}

STECKHAN, E ^{[1
]}

机构：

[1] UNIV BONN,INST ORGAN CHEM & BIOCHEM,D-53121 BONN,GERMANY

来源：

TETRAHEDRON LETTERS | 1994年 / 35卷 / 22期

关键词：

D O I：

10.1016/S0040-4039(00)73074-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Electrogenerated and regenerated silver(III)oxo bis(2,2'-bipyridine) and similar complexes can act as redox catalysts for the indirect electrochemical epoxidation of electron-deficient olefins in aqueous acetonitrile. Thus, isobutyl methacrylate is electrolyzed to form the epoxide with 87% material yield and 21% current yield.

引用

页码：3695 / 3698

页数：4

共 6 条

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[2] A KINETIC AND SPECTROPHOTOMETRIC EXAMINATION OF SILVER(2+ IN PERCHLORATE MEDIA [J].

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PEAT, FD ;

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[3]

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[4]

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[5] ELECTROCHEMICAL EPOXIDATION OF OLEFINS [J].

van der Eijk, J. M. ;

Peters, Th. J. ;

de Wit, N. ;

Colijn, H. A. .

CATALYSIS TODAY, 1988, 3 (2-3) :259-266

[6]

VANDEREIJK JM, 1987, PREPR AM CHEM SOC DI, V32, P827

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