SPECTROSCOPIC AND ELECTROCHEMICAL RESPONSE TO NITROGEN MONOXIDE OF A CATIONIC IRON PORPHYRIN IMMOBILIZED IN NAFION-COATED ELECTRODES OR MEMBRANES

被引：40

作者：

HAYON, J

OZER, D

RISHPON, J

BETTELHEIM, A

机构：

[1] NUCL RES CTR NEGEV,IL-84190 BEER SHEVA,ISRAEL

[2] TEL AVIV UNIV,DEPT BIOTECHNOL,IL-69978 RAMAT GAN,ISRAEL

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1994年 / 05期

关键词：

D O I：

10.1039/c39940000619

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nafion membranes containing immobilized Fell tetrakis(N-methyl-4-pyridyl)porphyrin show spectroscopic changes in the UV-VIS range after exposure to gaseous NO, indicating the formation of a nitrosyl complex; electroreduction of NO is mediated by this metalloporphyrin when immobilized in Nafion-coated glassy-carbon electrodes and the use of these film electrodes for the amperometric determination of NO in agueous solutions is demonstrated.

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页码：619 / 620

页数：2

相关论文

共 9 条

[1] ELECTROCATALYTIC REDUCTION OF NITRITE TO NITROUS-OXIDE AND AMMONIA BASED ON THE N-METHYLATED, CATIONIC IRON PORPHYRIN COMPLEX [FEIII(H2O) (TMPYP)]5+ [J].

BARLEY, MH ;

RHODES, MR ;

MEYER, TJ .

INORGANIC CHEMISTRY, 1987, 26 (11) :1746-1750

[2] BIOCONVERSION OF LIGHT ENERGY INTO CHEMICAL ENERGY THROUGH REDUCTION WITH WATER OF NITRATE TO AMMONIA [J].

CANDAU, P ;

MANZANO, C ;

LOSADA, M .

NATURE, 1976, 262 (5570) :715-717

[3] OXIDATION OF NITROGEN-OXIDES BY BOUND DIOXYGEN IN HEMOPROTEINS [J].

DOYLE, MP ;

HOEKSTRA, JW .

JOURNAL OF INORGANIC BIOCHEMISTRY, 1981, 14 (04) :351-358

[4] APPLICATION OF NAFION AS A POLYMER SOLID ELECTROLYTE FOR VOLTAMMETRY IN THE ABSENCE OF A CONTACTING ELECTROLYTE SOLUTION [J].

HARTH, R ;

MOR, U ;

OZER, D ;

BETTELHEIM, A .

JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1989, 136 (12) :3863-3867

[5] ELECTROCATALYTIC PROPERTIES OF CHEMICALLY POLYMERIZED FILMS OF COBALT, IRON AND MANGANESE TETRAKIS(O-AMINOPHENYL)PORPHYRINS [J].

HAYON, J ;

RAVEH, A ;

BETTELHEIM, A .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1993, 359 (1-2) :209-221

[6] NITRIC-OXIDE RELEASE FROM A SINGLE CELL MEASURED INSITU BY A PORPHYRINIC-BASED MICROSENSOR [J].

MALINSKI, T ;

TAHA, Z .

NATURE, 1992, 358 (6388) :676-678

[7] THE INFLUENCE OF THE POLYMER STRUCTURE ON ELECTROCHEMICAL PROPERTIES OF UNCHARGED MOLECULES IN NAFION FILMS ON ELECTRODES [J].

RUBINSTEIN, I .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1985, 188 (1-2) :227-244

[8] BIOCHEMISTRY OF NITRIC-OXIDE AND ITS REDOX-ACTIVATED FORMS [J].

STAMLER, JS ;

SINGEL, DJ ;

LOSCALZO, J .

SCIENCE, 1992, 258 (5090) :1898-1902

[9] ELECTROCATALYTIC REDUCTION OF NITRITE AND NITROSYL BY IRON(III) PROTOPORPHYRIN-IX DIMETHYL ESTER IMMOBILIZED IN AN ELECTROPOLYMERIZED FILM [J].

YOUNATHAN, JN ;

WOOD, KS ;

MEYER, TJ .

INORGANIC CHEMISTRY, 1992, 31 (15) :3280-3285