ELECTROCATALYTIC REDUCTION OF NITRITE AND NITROSYL BY IRON(III) PROTOPORPHYRIN-IX DIMETHYL ESTER IMMOBILIZED IN AN ELECTROPOLYMERIZED FILM

被引：198

作者：

YOUNATHAN, JN ^{[1
]}

WOOD, KS ^{[1
]}

MEYER, TJ ^{[1
]}

机构：

[1] UNIV N CAROLINA,DEPT CHEM,CHAPEL HILL,NC 27599

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 15期

关键词：

D O I：

10.1021/ic00041a022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thin polymeric films formed by anodic electropolymerization of an iron(III) protoporphyrin IX dimethyl ester complex, [Fe(III)(PP)Cl], on glassy-carbon or optically transparent SnO2 electrodes are effective catalysts for the electroreduction of HONO/NO2- or NO to N2O, N2, NH2OH, and NH3. The yield of N2 is enhanced in the compact environment of the redox polymer relative to that for comparable monomeric metalloporphyrins in homogeneous solution.

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页码：3280 / 3285

页数：6

相关论文

共 48 条

[1] ON PREPARATION OF METALLOPORPHYRINS [J].

ADLER, AD ;

LONGO, FR ;

KAMPAS, F ;

KIM, J .

JOURNAL OF INORGANIC & NUCLEAR CHEMISTRY, 1970, 32 (07) :2443-&

[2] CONTROLLED MECHANISMS OF ELECTRON-TRANSFER REDUCTION OF COORDINATED NITROSYLS [J].

ARMOR, J .

INORGANIC CHEMISTRY, 1973, 12 (08) :1959-1961

[3]

ARMOR JN, 1975, Z INORG CHEM, V14, P444

[4]

AVERILL BA, 1978, MTAL IONS BIOL SYSTE, V7, pCH4

[5] CRYSTAL AND MOLECULAR-STRUCTURE OF THE ISOBACTERIOCHLORIN - (2,3,7,8-TETRAHYDRO-5,10,15,20-TETRAPHENYLPORPHINATO)(PYRIDINE)ZINC(II) BENZENE SOLVATE [J].

BARKIGIA, KM ;

FAJER, J ;

SPAULDING, LD ;

WILLIAMS, GJB .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1981, 103 (01) :176-181

[6] IRON PORPHYRIN-BASED ELECTROCATALYTIC REDUCTION OF NITRITE TO AMMONIA [J].

BARLEY, MH ;

TAKEUCHI, K ;

MURPHY, WR ;

MEYER, TJ .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1985, (08) :507-508

[7] ELECTROCATALYTIC REDUCTION OF NITRITE TO AMMONIA BASED ON A WATER-SOLUBLE IRON PORPHYRIN [J].

BARLEY, MH ;

TAKEUCHI, KJ ;

MEYER, TJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (19) :5876-5885

[8] ELECTROCATALYTIC REDUCTION OF NITRITE TO NITROUS-OXIDE AND AMMONIA BASED ON THE N-METHYLATED, CATIONIC IRON PORPHYRIN COMPLEX [FEIII(H2O) (TMPYP)]5+ [J].

BARLEY, MH ;

RHODES, MR ;

MEYER, TJ .

INORGANIC CHEMISTRY, 1987, 26 (11) :1746-1750

[9] ELECTROCHEMICAL STUDIES OF INORGANIC REDOX PROCESSES IN N-BUTYRONITRILE OVER A WIDE-RANGE OF TEMPERATURE AND SCAN RATES AT CONVENTIONAL AND MICROSIZED ELECTRODES - IRON PROTOPORPHYRIN-IX DIMETHYL ESTER CHLORIDE [J].

BOND, AM ;

MANN, TF ;

TONDREAU, GA ;

SWEIGART, DA .

INORGANICA CHIMICA ACTA, 1990, 169 (02) :181-188

[10] ELECTROPHILIC BEHAVIOR OF NITROSYLS - PREPARATION AND REACTIONS OF 6-CO-ORDINATE RUTHENIUM TETRA(PYRIDINE) NITROSYL COMPLEXES [J].

BOTTOMLEY, F ;

MUKAIDA, M .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1982, (10) :1933-1937

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