ELECTROCATALYTIC REDUCTION OF NITRITE AND NITROSYL BY IRON(III) PROTOPORPHYRIN-IX DIMETHYL ESTER IMMOBILIZED IN AN ELECTROPOLYMERIZED FILM

被引：198

作者：

YOUNATHAN, JN ^{[1
]}

WOOD, KS ^{[1
]}

MEYER, TJ ^{[1
]}

机构：

[1] UNIV N CAROLINA,DEPT CHEM,CHAPEL HILL,NC 27599

来源：

INORGANIC CHEMISTRY | 1992年 / 31卷 / 15期

关键词：

D O I：

10.1021/ic00041a022

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thin polymeric films formed by anodic electropolymerization of an iron(III) protoporphyrin IX dimethyl ester complex, [Fe(III)(PP)Cl], on glassy-carbon or optically transparent SnO2 electrodes are effective catalysts for the electroreduction of HONO/NO2- or NO to N2O, N2, NH2OH, and NH3. The yield of N2 is enhanced in the compact environment of the redox polymer relative to that for comparable monomeric metalloporphyrins in homogeneous solution.

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页码：3280 / 3285

页数：6

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