Mineralomimetic chemistry of cyanometallates

被引：26

作者：

Iwamoto, T ^{[1
]}

Nishikiori, S ^{[1
]}

Kitazawa, T ^{[1
]}

机构：

[1] TOHO UNIV, FAC SCI, DEPT CHEM, FUNABASHI, CHIBA 274, JAPAN

来源：

SUPRAMOLECULAR CHEMISTRY | 1995年 / 6卷 / 1-2期

关键词：

D O I：

10.1080/10610279508032534

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structural similarity between Cd-x(CN)(y) and SixOy in the A(x)B(y) composition, A taking tetrahedral positions linked successively with B to build up multi-dimensional structures such as 1D-chains, 2D-layers, or 3D-lattices, can be utilized in developing mineral-like but unprecedented inclusion or supramolecular structures using cadmium cyanide and cyanocadmate moieties as building blocks, Examples have been demonstrated with single crystal structures for such inclusion structures as silica-mimetic Cd(CN)(2) host clathrates, clay-mimetic 2D-layer and zeolite-mimetic 3D-lattice cyanocadmate host inclusion compounds.

引用

页码：179 / 186

页数：8

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