SYNTHESIS AND STEREOCHEMISTRY OF DESACETOXYMATRICARIN AND STEREOCHEMISTRY OF MATRICARIN

被引：50

作者：

WHITE, EH

EGUCHI, S

MARX, JN

机构：

[1] Department of Chemistry, The Johns Hopkins University, Baltimore

来源：

TETRAHEDRON | 1969年 / 25卷 / 10期

关键词：

D O I：

10.1016/S0040-4020(01)82761-7

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Desacetoxymatricarin (IV), a sesquiterpene lactone found in the genus Artemisia and in the form of 8-hydroxy and acetoxy derivatives in the genus Achillea, has been synthesized from α-santonin by a sequence that allows assignment of the full stereochemistry. The stereochemistry of matricarin (V) has also been determined. The unusual stability to dehydration of some of the cyclopentyl-type alcohols, which were intermediates in the synthesis, is discussed. © 1969.

引用

页码：2099 / +

页数：1

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