DEALKYLATION OF THIOLS BY A PHOSPHIDO-BRIDGED DIMOLYBDENUM COMPLEX - CRYSTAL-STRUCTURE OF [MO2(MU-S)2(MU-SIPR)(MU-PPH2)(ETA-C5H5)2]

被引:17
作者
ADAMS, H [1 ]
BAILEY, NA [1 ]
BISSON, AP [1 ]
MORRIS, MJ [1 ]
机构
[1] UNIV SHEFFIELD,DEPT CHEM,SHEFFIELD S3 7HF,S YORKSHIRE,ENGLAND
关键词
D O I
10.1016/0022-328X(93)83092-A
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reaction of the phosphido, hydrido-bridged complex [Mo2(A-H)(mu-PPh2)(CO)4(eta-C5H5)2] With thiols RSH (R = (i)Pr, p-C6H4Me) or Me2S2 (for R = Me) in refluxing toluene gives moderate yields of the novel quadruply-bridged species [Mo2(mu-S)2(mu-SR)(mu-PPh2)(eta-C5H5)2]; the complex with R = (i)Pr has been structurally characterised.
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页码:C34 / C36
页数:3
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