HIGH-RESOLUTION SPECTRUM AND ANALYSIS OF 2-NU3 OF (CH4)-C-13 AT 1.67 UM

被引：20

作者：

FOX, K ^{[1
]}

HALSEY, GW ^{[1
]}

JENNINGS, DE ^{[1
]}

机构：

[1] NASA,GODDARD SPACE FLIGHT CTR,GREENBELT,MD 20771

来源：

JOURNAL OF MOLECULAR SPECTROSCOPY | 1980年 / 83卷 / 01期

基金：

美国国家航空航天局;

关键词：

Chemical analysis;

D O I：

10.1016/0022-2852(80)90322-7

中图分类号：

O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];

学科分类号：

070203 ; 070304 ; 081704 ; 1406 ;

摘要：

The 2v3 vibration-rotation overtone of 13CH 4 near 6000 cm-1 has been recorded at 0.025-cm -1 resolution and analyzed for the first time. Nineteen spectroscopic constants have been determined with a new algorithm developed to fit simultaneously the P-, Q-, and R-branches of spherical-top molecules. This algorithm has also been used to refine the analysis of 2ν3 of 12CH4. Copyright © 1980 by Academic Press, Inc.

引用

页码：213 / 222

页数：10

共 30 条

[11]

Fox K., 1972, Molecular Spectroscopy: Modern Research, P79

[12]

FOX K, 1962, THESIS U MICHIGAN

[13] ORBITAL LEVEL SPLITTING IN OCTAHEDRAL SYMMETRY AND SF6 ROTATIONAL SPECTRA .1. QUALITATIVE FEATURES OF HIGH J LEVELS [J].