X-RAY CRYSTAL-STRUCTURE OF [(MO2AG6S6[SCME3]2)(O)2(PH3P)4], A 1ST DOUBLE CUBANE-LIKE COMPOUND OF THE MO-AG-S SYSTEM

被引：18

作者：

DU, SW

ZHU, NY

CHEN, PC

WU, XT

机构：

[1] Fuzhou Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences

来源：

POLYHEDRON | 1992年 / 11卷 / 19期

关键词：

D O I：

10.1016/S0277-5387(00)83568-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel Mo-Ag-S double cubane-like heterometallic compound, [{Mo2Ag6 S6[SCMe3]2}(O)2(Ph3P)4], has been obtained from the reaction of the butterfly-like compound {MoAg2S3}(O)(Ph3P)3 with AgSCMe3 in CH2Cl2 solvent. The title complex has been characterized by X-ray crystallography. In the complex, two cubane-like fragments are linked by two Ag-SCMe3 bonds, in which the SCMe3- ligand acts as a triple bridge. Three Ag-SCMe bonds were found to be 2.389(3), 2.525(3), and 2.644(3) angstrom respectively.

引用

页码：2489 / 2493

页数：5

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