COPPER-DIOXYGEN REACTIVITY INVOLVED IN THE FORMATION OF MU-OXO [(POR)FE-III-O-CU(III)L](+) HETERODINUCLEAR COMPLEXES (POR=PORPHYRINATE, L=TETRADENTATE LIGAND), AND NOVEL SYNTHESIS OF SQUARE-PLANAR FE-II(POR) SPECIES

被引：16

作者：

NANTHAKUMAR, A ^{[1
]}

FOX, S ^{[1
]}

KARLIN, KD ^{[1
]}

机构：

[1] JOHNS HOPKINS UNIV,DEPT CHEM,BALTIMORE,MD 21218

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1995年 / 04期

关键词：

D O I：

10.1039/c39950000499

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the reaction of Fe-II(por) species with [LCu(I)(MeCN)](+) and O-2 to give mu-oxo [(por)Fe-III-O-Cu(II)L](+) 3 (per = porphyrinate, L = tetradentate ligand), copper-dioxygen adducts or their decomposition products must be present, otherwise [(por)Fe-III-OH] or [(por)Fe-III-O-Fe-III(por)] products appear; a novel synthesis of square-planar Fe-II(por) is also described.

引用

页码：499 / 501

页数：3

共 16 条

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