NOVEL ELECTRON-DONORS FOR ORGANIC CONDUCTORS - BENZO[C]THIOPHENE-EXTENDED ANALOGS OF METHYLENEDITHIOTETRAFULVALENE, ETHYLENEDITHIOTETRATHIAFULVALENE, PROPYLENEDITHIOTETRATHIAFULVALENE

被引：10

作者：

TAKAHASHI, K

ISE, T

机构：

来源：

CHEMISTRY LETTERS | 1995年 / 01期

关键词：

D O I：

10.1246/cl.1995.77

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three alkylenedithio derivatives of 1,3-bis(1,3-dithiol-2-ylidene)-1,3-dihydrobenzo[c]thiophene (BDTBT) have been synthesized. These donors exhibited an electron-donating ability near to that of tetrathiafulvalene and afforded a very stable radical cation. The powdered tetracyanoquinodimethane complex of the methylenedithio derivative exhibited a fairly high room temperature conductivity of sigma=15 Scm(-1) and a semiconducting behavior with a very low activation energy of Ea=0.050 eV.

引用

收藏

页码：77 / 78

页数：2

相关论文

共 22 条

[1] ETHENEDIYLIDENE-2,2'-BIS(1,3-DITHIOLE) AND BUTATRIENE-1,4-DIYLIDENE-2,2'-BIS(1,3-DITHIOLE) [J].

AWAJI, H ;

SUGIMOTO, T ;

YOSHIDA, ZI .

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1988, 1 (01) :47-51

[2] STRUCTURES OF 2 SEMICONDUCTING CHARGE-TRANSFER SALTS BASED ON 4,5-METHYLENEDITHIO-4',5'-PROPYLENEDITHIOTETRATHIAFULVALENE (MPT) (MPT)2CLO4(THF) AND (MPT)2PF6(THF) [J].

BENO, MA ;

KINI, AM ;

WANG, HH ;

TYTKO, SF ;

CARLSON, KD ;

WILLIAMS, JM .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1988, 44 :1223-1227

[3] ELECTRICAL AND MAGNETIC-PROPERTIES AND X-RAY STRUCTURE OF A HIGHLY CONDUCTIVE 4-1 COMPLEX OF TETRACYANOQUINODIMETHANE AND A TETRATHIAFULVALENE DERIVATIVE [J].

BRYCE, MR ;

MOORE, AJ ;

HASAN, M ;

ASHWELL, GJ ;

FRASER, AT ;

CLEGG, W ;

HURSTHOUSE, MB ;

KARAULOV, AI .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1990, 29 (12) :1450-1452

[4] DESIGN AND SYNTHESIS OF ORGANIC METALS [J].

GARITO, AF ;

HEEGER, AJ .

ACCOUNTS OF CHEMICAL RESEARCH, 1974, 7 (07) :232-240

[5] NEW EXTENDED PI-ELECTRON DONORS - TETRATHIAFULVALENE SYSTEMS WITH HETEROCYCLIC SPACER GROUPS [J].

HANSEN, TK ;

LAKSHMIKANTHAM, MV ;

CAVA, MP ;

NIZIURSKIMANN, RE ;

JENSEN, F ;

BECHER, J .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (13) :5035-5039

[6] HIGHLY CONJUGATED PI-ELECTRON DONORS FOR ORGANIC METALS - SYNTHESIS AND REDOX CHEMISTRY OF NEW 1,3-DITHIOLE AND 1,3-SELENATHIOLE DERIVATIVES [J].

MOORE, AJ ;

BRYCE, MR .

JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1991, (01) :157-168

[7]

PAPAVASSILIOU GC, 1988, SYNTHETIC MET, V27, P379

[8] NEW DONORS FOR ORGANIC METALS [J].

SUGIMOTO, T ;

AWAJI, H ;

SUGIMOTO, I ;

MISAKI, Y ;

YOSHIDA, Z .

SYNTHETIC METALS, 1987, 19 (1-3) :569-572

[9] 1ST AMBIENT-PRESSURE SUPERCONDUCTOR BASED ON NI(DMIT)(2), ALPHA-EDT-TTF[NI(DMIT)(2)] [J].

TAJIMA, H ;

INOKUCHI, M ;

KOBAYASHI, A ;

OHTA, T ;

KATO, R ;

KOBAYASHI, H ;

KURODA, H .

CHEMISTRY LETTERS, 1993, (07) :1235-1238

[10] CONJUGATION-EXTENDED TETRATHIAFULVALENE ANALOGS INVOLVING A CENTRAL AROMATIC 5-MEMBERED HETEROCYCLIC LINKING GROUP [J].

TAKAHASHI, K ;

NIHIRA, T ;

YOSHIFUJI, M ;

TOMITANI, K .

BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1993, 66 (08) :2330-2334