REACTION OF ALKYL IODIDES WITH PERACETIC ACID IN PRESENCE OF AROMATIC COMPOUNDS

被引：37

作者：

OGATA, Y

AOKI, K

机构：

[1] Department of Applied Chemistry, Faculty of Engineering, Nagoya University, Chikusa-ku, Nagoya

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1969年 / 34卷 / 12期

关键词：

D O I：

10.1021/jo01264a048

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Treatment of n-alkyl iodides with peracetic acid in the presence of aromatic compounds in acetic acid at 30° affords alkyl acetates and often iodo aromatic compounds in good yields. The rate of the reaction for a mixture of methyl iodide, peracetic acid, and m-xylene can be expressed as v — k[CH3I] [CH3CO3H] and is independent of the concentration of m-xylene. The structure of alkyl iodides affects the yield of iodoaromatic compound in the decreasing order n-alkyl > sec-alkyl > t-alkyl. The reaction mechanism is briefly discussed in terms of the effect of structure on the kinetics and product composition. © 1969, American Chemical Society. All rights reserved.

引用

页码：3974 / &

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