LOW-LYING ELECTRONICALLY EXCITED-STATES OF C-60 AND C-70 AND MEASUREMENT OF THEIR PICOSECOND TRANSIENT ABSORPTION IN SOLUTION

被引：118

作者：

LEE, M ^{[1
]}

SONG, OK ^{[1
]}

SEO, JC ^{[1
]}

KIM, D ^{[1
]}

SUH, YD ^{[1
]}

JIN, SM ^{[1
]}

KIM, SK ^{[1
]}

机构：

[1] SEOUL NATL UNIV,DEPT CHEM,SEOUL 151742,SOUTH KOREA

来源：

CHEMICAL PHYSICS LETTERS | 1992年 / 196卷 / 3-4期

关键词：

D O I：

10.1016/0009-2614(92)85976-H

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Low-lying electronically excited states of C60 and C70 were identified in picosecond transient absorption measurements extending in wavelength down to 1000 nm. Spectral features in the near-infrared region were found to be significantly different from the results of previous studies. The lifetimes for S1 states of C60 and C70 Were determined to be 1.3+/-0.2 ns and 0.7+/-0.05 ns, respectively. A simple energy diagram for electronic states of C60 and C70 is presented.

引用

页码：325 / 329

页数：5

共 20 条

[1] CHARACTERIZATION OF THE SOLUBLE ALL-CARBON MOLECULES C60 AND C70
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[2] PHOTOPHYSICAL PROPERTIES OF C60
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[3] PHOTOPHYSICAL PROPERTIES OF C-70
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[4] EXCITED-STATE PROPERTIES OF C60
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[5] THE MAGNETIC CIRCULAR-DICHROISM AND ABSORPTION-SPECTRA OF C60 ISOLATED IN AR MATRICES
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[6] PREPARATION AND UV VISIBLE SPECTRA OF FULLERENES C60 AND C70
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[J]. CHEMICAL PHYSICS LETTERS, 1991, 177 (4-5) : 394 - 398
[7] FULLERENE TRIPLET-STATE PRODUCTION AND DECAY - R2PI PROBES OF C60 AND C70 IN A SUPERSONIC BEAM
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[J]. CHEMICAL PHYSICS LETTERS, 1991, 179 (5-6) : 449 - 454
[8] EFFICIENT PRODUCTION OF C60 (BUCKMINSTERFULLERENE), C60H36, AND THE SOLVATED BUCKIDE ION
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HALEY, MM
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[9] TRANSIENT ABSORPTION, LIFETIME AND RELAXATION OF C60 IN THE TRIPLET-STATE
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[10] KIM D, IN PRESS J AM CHEM S

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