EASY METALATION OF THE SUBSTITUTED DIMETHYL SULFIDE MESCH(2)R (R=C(O)OET) BY PALLADIUM ACETATE AND CHARACTERIZATION OF THE TRINUCLEAR MIXED-SPHERE [PD-3(MU-O(2)CME)(3)(MU-MESCHR)(3)] COMPLEX

被引：20

作者：

BASATO, M

GRASSI, A

VALLE, G

机构：

[1] UNIV SALERNO, DIPARTIMENTO CHIM, I-84081 BARONISSI, ITALY

[2] CNR, CTR STUDIO BIOPOLIMERI, I-35131 PADUA, ITALY

来源：

ORGANOMETALLICS | 1995年 / 14卷 / 09期

关键词：

D O I：

10.1021/om00009a059

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Palladium acetate reacts with the weak carbon. acid MeSCH(2)R (R = C(O)OEt) to give [Pd-3(mu-O(2)CMe)(3)(mu-MeSCHR)(3)] (1), characterized by X-ray crystallography. The MeSCHC(O)OEt(-) anion acts as a bidentate Ligand binding two palladium atoms via a (Me)SCH(R) bridge, in which the methine carbon. is chiral. Complex 1 is the first mixed-sphere palladium complex in which the solid-state nuclearity and structure of palladium acetate is retained.

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页码：4439 / 4442

页数：4

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