共 14 条
- [11] KENNEDY JD, 1978, 19 P INT C COORD CHE, V1, P79
- [12] MUETTERTIES EL, 1972, PURE APPL CHEM, V29, P585
- [13] RIETZ RR, 1973, J AM CHEM SOC, V95, P4580, DOI 10.1021/ja00795a020
- [14] SHORE SN, COMMUNICATION
NMR-STUDIES ON HALOGENO-CIS-BIS(PHOSPHINE)-NIDO-PENTABORANYL DERIVATIVES OF NICKEL, PALLADIUM, AND PLATINUM
被引：66
作者：
KENNEDY, JD
STAVES, J
机构：
[1] Department of Inorganic and Structural Chemistry, University of Leeds
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES
|
1979年
/
34卷
/
06期
关键词：
Double Resonance;
Metalloboranes;
Multinuclear NMR;
Relaxation;
D O I：
10.1515/znb-1979-0610
中图分类号：
O61 [无机化学];
学科分类号：
070301 ;
081704 ;
摘要：
An examination of the 1H-{11B}, 11B-{1H}, and 31P-{1H} NMR behaviour of the compounds [M(B5H8)(X)(dppe)] has been made [M = Ni, Pd and Pt; X = halogen; dppe = bis(diphenylphosphino)ethane]. Some relaxation phenomena are rationalised, and it is concluded that all the compounds examined have a static metallo-nido-penta-borane structure in which the metal atom occupies a bridging position between two basal boron atoms. Some temperature and solvent effects are also presented and briefly discussed. © 1979, Walter de Gruyter. All rights reserved.
引用
收藏
页码：808 / 813
页数：6
相关论文