SELECTIVE INTRAMOLECULAR CLEAVAGE OF THE CARBON SILICON BOND BY PALLADIUM SALTS

被引：31

作者：

VALK, JM ^{[1
]}

BOERSMA, J ^{[1
]}

VANKOTEN, G ^{[1
]}

机构：

[1] UNIV UTRECHT,DEBYE INST,DEPT MET MEDIATED SYNTH,PADUALAAN 8,3584 CH UTRECHT,NETHERLANDS

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 483卷 / 1-2期

关键词：

PALLADIUM; SILICON;

D O I：

10.1016/0022-328X(94)87166-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Several (aryl)trimethylsilane derivatives containing a potentially intramolecularly coordinating dimethylaminomethyl group were prepared and treated with Li2PdCl4 or Pd(OAc)2. Highly selective cleavage of the aryl-C-Si bond took place to give the corresponding arylpalladium complexes. Similar reactions were observed for benzylic trimethylsilyl compounds. The yields of the reactions with Li2PdCl4 varied from 66 to 94%, but yields were >90% when Pd(OAc)2 was used.

引用

页码：213 / 216

页数：4