CATION INCLUSION WITHIN THE MIXED-VALENCE POLYANION CLUSTER [((MOO3)-O-VI)4MO(12)(V)O(28)(OH)(12)](8-) - SYNTHESES AND STRUCTURES OF (NH4)7[NAMO16(OH)12O40]CENTER-DOT-4H2O AND (ME(2)NH(2))(6)[H2MO16(OH)12O40]

被引:75
作者
KHAN, MI
MULLER, A
DILLINGER, S
BOGGE, H
CHEN, Q
ZUBIETA, J
机构
[1] UNIV BIELEFELD,FAK CHEM,D-33501 BIELEFELD 1,GERMANY
[2] SYRACUSE UNIV,DEPT CHEM,SYRACUSE,NY 13244
来源
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH | 1993年 / 32卷 / 12期
关键词
D O I
10.1002/anie.199317801
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A flexible ϵ‐Keggin (Mo12O40) core that can encapsulate either two protons or a Na+ ion is found in the title compounds. In the Na compound (shown on the right) the Na+ guest has the unusual coordination number of four. (Figure Presented.) Copyright © 1993 by VCH Verlagsgesellschaft mbH, Germany
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页码:1780 / 1782
页数:3
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