SUPPORTED AQUEOUS-PHASE, RHODIUM HYDROFORMYLATION CATALYSTS .2. HYDROFORMYLATION OF LINEAR, TERMINAL AND INTERNAL OLEFINS

被引：60

作者：

ARHANCET, JP

DAVIS, ME

HANSON, BE

机构：

[1] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM ENGN,BLACKSBURG,VA 24061

[2] VIRGINIA POLYTECH INST & STATE UNIV,DEPT CHEM,BLACKSBURG,VA 24061

来源：

JOURNAL OF CATALYSIS | 1991年 / 129卷 / 01期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/0021-9517(91)90013-T

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Hydroformylation of 1-, 2-, and 3-heptene by supported aqueous-phase (SAP) catalysts shows that the conversion to aldehydes and the regioselectivity are functions of the position of the double bond. I-Tetradecene and 1-heptadecene give results similar to 1-heptene while data obtained from t-7-tetradecene compare well to those observed from t-2-heptene indicating the independence of chain length. Linear dienes are shown to be hydroformylated as well. Effects of temperature and pressure and water content are illustrated using linear, terminal, and internal olefins. © 1991.

引用

页码：100 / 105

页数：6