ENANTIOMER SEPARATION USING MOBILE AND IMMOBILE CYCLODEXTRIN DERIVATIVES WITH ELECTROMIGRATION

被引：75

作者：

MAYER, S ^{[1
]}

SCHURIG, V ^{[1
]}

机构：

[1] UNIV TUBINGEN,INST ORGAN CHEM,D-72076 TUBINGEN,GERMANY

来源：

ELECTROPHORESIS | 1994年 / 15卷 / 06期

关键词：

D O I：

10.1002/elps.11501501118

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

The principle of electrochromatography is applied to enantiomer separation with wall-coated capillaries of 50 mu m (ID). As chiral stationary phase an immobilized polysiloxane containing chemically bonded monokis-6-O-octamethylene-permethyl-cyclodextrin (beta- or gamma-Chirasil-Dex) was used. The results are compared with the conventional method of adding cyclodextrin derivatives as chiral pseudostationary phase to the running buffer.

引用

页码：835 / 841

页数：7

共 18 条

[1] DERIVATIZED CYCLODEXTRINS IMMOBILIZED ON FUSED-SILICA CAPILLARIES FOR ENANTIOMERIC SEPARATIONS VIA CAPILLARY ELECTROPHORESIS, GAS-CHROMATOGRAPHY, OR SUPERCRITICAL FLUID CHROMATOGRAPHY
ARMSTRONG, DW
TANG, YB
WARD, T
NICHOLS, M
[J]. ANALYTICAL CHEMISTRY, 1993, 65 (08) : 1114 - 1117
[2] USE OF CYCLODEXTRINS IN CAPILLARY ZONE ELECTROPHORESIS - RESOLUTION OF TERBUTALINE AND PROPRANOLOL ENANTIOMERS
FANALI, S
[J]. JOURNAL OF CHROMATOGRAPHY, 1991, 545 (02): : 437 - 444
[3] SEPARATION OF OPTICAL ISOMERS BY CAPILLARY ZONE ELECTROPHORESIS BASED ON HOST GUEST COMPLEXATION WITH CYCLODEXTRINS
FANALI, S
[J]. JOURNAL OF CHROMATOGRAPHY, 1989, 474 (02): : 441 - 446
[4] ENANTIOMERIC SEPARATION BY GC ON CHIRASIL-DEX - SYSTEMATIC STUDY OF CYCLODEXTRIN CONCENTRATION, POLARITY, IMMOBILIZATION, AND COLUMN STABILITY
JUNG, M
SCHURIG, V
[J]. JOURNAL OF MICROCOLUMN SEPARATIONS, 1993, 5 (01) : 11 - 22
[5] CHIRAL SEPARATION BY CAPILLARY ELECTROPHORESIS
KUHN, R
HOFFSTETTERKUHN, S
[J]. CHROMATOGRAPHIA, 1992, 34 (9-10) : 505 - 512
[6] CAPILLARY ZONE ELECTROPHORESIS - EFFECT OF PHYSICAL PARAMETERS ON SEPARATION EFFICIENCY AND QUANTITATION
LUKACS, KD
JORGENSON, JW
[J]. JOURNAL OF HIGH RESOLUTION CHROMATOGRAPHY & CHROMATOGRAPHY COMMUNICATIONS, 1985, 8 (08): : 407 - 411
[7] DUAL CHIRAL RECOGNITION SYSTEM INVOLVING CYCLODEXTRIN DERIVATIVES IN CAPILLARY ELECTROPHORESIS
MAYER, S
SCHLEIMER, M
SCHURIG, V
[J]. JOURNAL OF MICROCOLUMN SEPARATIONS, 1994, 6 (01) : 43 - 48
[8] ENANTIOMER SEPARATION BY ELECTROCHROMATOGRAPHY IN OPEN TUBULAR COLUMNS COATED WITH CHIRASIL-DEX
MAYER, S
SCHURIG, V
[J]. JOURNAL OF LIQUID CHROMATOGRAPHY, 1993, 16 (04): : 915 - 931
[9] MAYER S, 1993, THESIS U TUBINGEN
[10] Mayer S., 1992, J HIGH RES CHROMATOG, V15, P129, DOI DOI 10.1002/JHRC.1240150216

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