THE RHODIUM CARBENOID ROUTE TO CYCLIC ETHERS - SYNTHESIS OF THE CIS-2,7-DISUBSTITUTED OXEPANE SKELETON OF ISOLAUREPINNACIN

被引:34
作者
DAVIES, MJ [1 ]
MOODY, CJ [1 ]
机构
[1] IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM,LONDON SW7 2AY,ENGLAND
来源
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1 | 1991年 / 01期
关键词
D O I
10.1039/p19910000009
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The cis-2,7-disubstituted oxepane skeleton 1 of the marine natural product isolaurepinnacin 2 has been obtained by three routes, all of which involve a rhodium (II) acetate mediated cyclisation of diazo alcohols to give the functionalised oxepanes 3, 4 and 5, suitable for further elaboration into the common intermediate, the oxepan-3-one 8.
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页码:9 / 12
页数:4
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