ALKALI-METAL SALTS OF PERFLUORINATED COMPLEX ANIONS - EFFECTIVE REAGENTS FOR NUCLEOPHILIC FLUORINATION

被引：22

作者：

FAROOQ, O

TIERS, GVD

机构：

[1] Graphic Research & Science Research Laboratories, 3M Central Research, St. Paul, Minnesota 55144

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 08期

关键词：

D O I：

10.1021/jo00087a031

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Alkali metal salts:of perfluorinated complex anions were used to effect halogen-exchange fluorination in organohalosilanes both in the presence and absence of solvent. By the use of salts of perfluorinated ''non-nucleophilic'' anions in a high-boiling multifunctional etheral solvent, organofluorosilanes have been conveniently prepared in high yields.

引用

页码：2122 / 2124

页数：3

共 32 条

[21]

NGUYENDUCCHUY, 1975, COLLECT CZECH CHEM C, V40, P875

[22]

NIKITIN EV, 1983, ZH OBSHCH KHIM+, V53, P230

[23] AROMATIC-SUBSTITUTION .57. NITRATION OF PHENYLBORON DICHLORIDE WITH NITRONIUM TETRAFLUOROBORATE - ATTEMPTED NITRATION OF IODOBENZENE DICHLORIDE AND PHENYLPHOSPHORUS DICHLORIDE [J].