CHEMISTRY OF ORGANOSILICON COMPOUNDS .118. NOVEL RING CONTRACTION REACTION OF (ETA-4-1,2-DISILACYCLOHEXADIENE) IRON TRICARBONYLS

被引：37

作者：

NAKADAIRA, Y

KOBAYASHI, T

SAKURAI, H

机构：

[1] Department of Chemistry, Faculty of Science, Tohoku University, Sendai

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1979年 / 165卷 / 03期

关键词：

D O I：

10.1016/S0022-328X(00)82209-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

1,1,2,2-Dimethyl-3,6-diphenyl-1,2-disilacyclohexadiene reacts with iron pentacarbonyl or diiron nonacarbonyl to give the corresponding (diene)iron tricarbonyl complex which undergoes novel ring contraction reaction to (η4-1,1-dimethyl-2,5-diphenyl-1-silacyclopentadiene)iron tricarbonyl on thermolysis at 160°C. Similar results were observed with 1,1,2,2-tetramethyl-3,4,5,6-tetraphenyl-1,2-disilacyclohexadiene. © 1979.

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页码：399 / 405

页数：7

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