PARTIAL OXIDATION OF UNSATURATED-HYDROCARBONS OVER PD(111) - OXYGEN SCAVENGING OF REACTIVE INTERMEDIATES AND THE FORMATION OF FURAN FROM C2H2 AND C4H4

被引：43

作者：

ORMEROD, RM ^{[1
]}

LAMBERT, RM ^{[1
]}

机构：

[1] UNIV CAMBRIDGE,DEPT CHEM,LENSFIELD RD,CAMBRIDGE CB2 1EW,ENGLAND

来源：

CATALYSIS LETTERS | 1990年 / 6卷 / 01期

关键词：

D O I：

10.1007/BF00764061

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Furan is formed by selective oxidation of both C2H2 and C4H4 over Pd(111). In the former case, oxygen scavenging of reactively formed C4H4 directly demonstrates that this species is the key intermediate in acetylene cyclotrimerisation. In the latter case, overall selectivity towards furan formation can be as high as ∼ 80%. © 1990 J.C. Baltzer A.G. Scientific Publishing Company.

引用

页码：121 / 130

页数：10

共 18 条

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