NEW METALORGANIC GALLIUM PRECURSORS FOR THE GROWTH OF GAAS AND ALGAAS BY CBE

被引:17
作者
JONES, AC [1 ]
LANE, PA [1 ]
MARTIN, T [1 ]
FREER, RW [1 ]
CALCOTT, PDJ [1 ]
HOULTON, MR [1 ]
WHITEHOUSE, CR [1 ]
机构
[1] RSRE,DRA ELECTR DIV,GREAT MALVERN WR14 3PS,WORCS,ENGLAND
关键词
D O I
10.1016/0022-0248(92)90441-K
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The use of triethylgallium (TEGa) for the CBE growth of GaAs and AlGaAs leads -to, very significant reductions in unintentional carbon incorporation compared to corresponding layers grown using trimethylgallium (TMGa). However, in a continuing effort to generate even further reductions in impurity levels, the present paper provides the first reported comparison of the tri-isopropylgallium (TIPGa) and tri-tertiarybutylgallium (TTBGa) precursors for CBE growth applications. The use of TTBGa is found to lead to unacceptably low GaAs growth rates, an effect which is attributed to a steric influence on the chemisorption process. In contrast, the TIPGa-grown GaAs layers exhibit very important improvements in electrical and optical properties compared to corresponding TEGa-grown material. Results of initial AlGaAs growth experiments performed using TIPGa are also presented.
引用
收藏
页码:81 / 87
页数:7
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