A NEW TYPE OF PHOSPHABENZENE COORDINATION

被引：17

作者：

ARCE, AJ ^{[1
]}

DEEMING, AJ ^{[1
]}

DESANCTIS, Y ^{[1
]}

MANZUR, J ^{[1
]}

机构：

[1] UNIV LONDON UNIV COLL,DEPT CHEM,LONDON WC1H 0AJ,ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 03期

关键词：

D O I：

10.1039/c39930000325

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Phosphabenzene reacts with [OS3H2(CO)10] to give the compound [Os3(mu-H)2(mu3-C5H5P)(CO)9] (X-ray structure of the 2-tert-butyl substituted derivative is reported) containing a four-electron donating mu3-phosphabenzene ligand, and the phosphabenzene-coupled product, [Os3(mu-H)(mu3-C10H11P2)(CO)9] (X-ray structure is reported).

引用

页码：325 / 326

页数：2

共 15 条

[1] RELATIONSHIPS BETWEEN STRUCTURE AND LIGAND DYNAMICS IN ORGANOMETAL CLUSTERS [J].

AIME, S ;

GOBETTO, R ;

OSELLA, D ;

MILONE, L ;

ROSENBERG, E .

ORGANOMETALLICS, 1982, 1 (04) :640-644

[2] NONACARBONYL-DI-MU-HYDRIDO-(TRIPHENYLPHOSPHINE)-TRIANGULO-TRIOSMIUM [J].

BENFIELD, RE ;

JOHNSON, BFG ;

LEWIS, J ;

RAITHBY, PR ;

ZUCCARO, C ;

HENRICK, K .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1979, 35 (SEP) :2210-2212

[3] PHOTOCHEMICAL CONVERSION OF H2OS3(CO)10(P-DONOR) TO H2OS3(CO)9(P-DONOR) IN SOLUTION AND ON HIGH-SURFACE-AREA SILICA [J].

BENTSEN, JG ;

WRIGHTON, MS .

INORGANIC CHEMISTRY, 1984, 23 (05) :512-515

[4] TRICARBONYL(TRIPHENYLPHOSPHORINE)MOLYBDENUM(O) [J].

DEBERITZ, J ;

NOTH, H .

CHEMISCHE BERICHTE-RECUEIL, 1973, 106 (07) :2222-2226

[5] (TRIPHENYLPHOSPHORINE)CHROMIUM(O)TRICARBONYL [J].

DEBERITZ, J ;

NOTH, H .

CHEMISCHE BERICHTE-RECUEIL, 1970, 103 (08) :2541-&

[6] 2,4,6-TRIPHENYLPHOSPHORINE METAL(O) CARBONYL OF CHROMIUM, MOLYBDENUM AND TUNGSTEN [J].

DEBERITZ, J ;

NOTH, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1973, 49 (02) :453-467

[7] ADDITION-REACTIONS OF A POLYNUCLEAR OSMIUM HYDRIDO COMPOUND LEADING TO ASSOCIATIVE CARBONYL SUBSTITUTION AND CATALYTIC ALKENE ISOMERIZATION [J].

DEEMING, AJ ;

HASSO, S .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1976, 114 (03) :313-324

[8] REACTIONS OF TRICARBONYLCHROMIUM-ETA-6-LAMBDA-3-PHOSPHORIN COMPLEXES YIELDING TRICARBONYLCHROMIUM-ETA-6-LAMBDA-3-PHOSPHORIN YLIDE COMPLEXES [J].

DIMROTH, K ;

KALETSCH, H .

JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1983, 247 (03) :271-285

[9] METAL-PI-COMPLEXES OF HETEROARENES .3. BIS(ETA-6-PHOSPHABENZENE)VANADIUM - SYNTHESIS, STRUCTURE, REDOX PROPERTIES, AND CONFORMATIONAL FLEXIBILITY [J].

ELSCHENBROICH, C ;

NOWOTNY, M ;

METZ, B ;

MASSA, W ;

GRAULICH, J ;

BIEHLER, K ;

SAUER, W .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (05) :547-550

[10]

MARKL G, 1990, MULTIPLE BONDS LOW C, P220

← 1 2 →