AN UNPRECEDENTED RUTHENIUM ALLENYLIDENE COMPLEX CONTAINING AN UNSATURATED BICYCLIC SYSTEM - FORMAL ADDITION OF 1-ETHYNYL-1-CYCLOHEXANOL TO AN ALKENYLVINYLIDENE INTERMEDIATE COMPLEX

被引：58

作者：

CADIERNO, V

GAMASA, MP

GIMENO, J

LASTRA, E

BORGE, J

GARCIAGRANDA, S

机构：

[1] UNIV OVIEDO,FAC QUIM,DEPT QUIM ORGANOMET,E-33071 OVIEDO,SPAIN

[2] UNIV OVIEDO,FAC QUIM,DEPT QUIM FIS & ANALIT,E-33071 OVIEDO,SPAIN

来源：

ORGANOMETALLICS | 1994年 / 13卷 / 03期

关键词：

D O I：

10.1021/om00015a001

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The stoichiometric activation of 1-ethynyl-1-cyclohexanol by [RuCl(PPh3)2(eta-C9H7)] in the presence of NaPF6 allows the formation of the propadienylidene ruthenium complex 1, containing a new spirobicyclic system which is formed through an unprecedented coupling process. The crystal structure of 1 has been determined by X-ray diffraction crystallography.

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页码：745 / 747

页数：3

相关论文

共 11 条

[1]

ANTONOVA AB, 1989, RUSS CHEM REV, V58, P693, DOI DOI 10.1070/RC1989V058N07ABEH003471

[2] ORGANOMETALLIC CHEMISTRY OF VINYLIDENE AND RELATED UNSATURATED CARBENES [J].

BRUCE, MI .

CHEMICAL REVIEWS, 1991, 91 (02) :197-257

[3] ACTIVATION OF 2-PROPYN-1-OL DERIVATIVES BY (ARENE)RUTHENIUM(II) COMPLEXES - NEW ROUTE TO (ALKENYLCARBENE)METAL AND (POLYENYLCARBENE)METAL COMPLEXES [J].

PILETTE, D ;

OUZZINE, K ;

LEBOZEC, H ;

DIXNEUF, PH ;

RICKARD, CEF ;

ROPER, WR .

ORGANOMETALLICS, 1992, 11 (02) :809-817

[4] METALLACUMULENES - NEW ALLENYLIDENE-RUTHENIUM COMPLEXES - CRYSTAL-STRUCTURE OF A CATIONIC [(PH2PCH2PPH2)2(CL)RU=C=C=CR1R2]+ DERIVATIVE [J].

PIRIO, N ;

TOUCHARD, D ;

TOUPET, L ;

DIXNEUF, PH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (14) :980-982

[5] METALLACUMULENES - PREPARATION OF NOVEL ALKENYL-ALLENYLIDENE-RUTHENIUM AND DIYNYL-RUTHENIUM COMPLEXES - CRYSTAL-STRUCTURE OF A RU-C=C-C=C-C(OSIME3)PH2 DERIVATIVE [J].

ROMERO, A ;

PERON, D ;

DIXNEUF, PH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (20) :1410-1412

[6]

ROMERO A, 1990, ANGEW CHEM INT EDIT, V29, P215

[7]

ROMERO A, 1990, ANGEW CHEM, V102, P210

[8] SYNTHESIS AND STRUCTURE OF [RU(C3PH2)(PME3)2(CP)][PF6], A CATIONIC DIPHENYLALLENYLIDENE COMPLEX [J].

SELEGUE, JP .

ORGANOMETALLICS, 1982, 1 (01) :217-218

[9] REACTIONS OF [RUCL(PME3)2(CP)] WITH ALIPHATIC ALKYNOLS LEADING TO CATIONIC VINYLVINYLIDENE AND NEUTRAL ENYNYL COMPLEXES AND REACTIONS OF THE ENYNYLS WITH HETEROALLENES [J].

SELEGUE, JP ;

YOUNG, BA ;

LOGAN, SL .

ORGANOMETALLICS, 1991, 10 (06) :1972-1980

[10]

WERNER H, 1992, NACHR CHEM TECH LAB, V40, P435