VERTICAL 4-ELECTRON-DONOR ALKYNE LIGANDS IN (TRIS(3,5-DIMETHYLPYRAZOLYL)BORATO)NIOBIUM COMPLEXES

被引：35

作者：

ETIENNE, M ^{[1
]}

WHITE, PS ^{[1
]}

TEMPLETON, JL ^{[1
]}

机构：

[1] UNIV N CAROLINA,DEPT CHEM,CHAPEL HILL,NC 27599

来源：

ORGANOMETALLICS | 1991年 / 10卷 / 11期

关键词：

D O I：

10.1021/om00057a006

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reaction of NbCl3(DME)(PhC = CMe) with KTp' in THF produces a high yield of Tp'NbCl2(PhC = CMe). The solid-state structure of Tp'NbCl2(PhC = CMe) has the alkyne ligand in the molecular mirror plane, and NMR data are compatible with retention of this alkyne orientation in solution.

引用

页码：3801 / 3803

页数：3

共 11 条

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