ESTERIFICATION OF CARBOXYLIC-ACIDS WITH TRIALKYLOXONIUM SALTS

被引：53

作者：

RABER, DJ ^{[1
]}

GARIANO, P ^{[1
]}

BROD, AO ^{[1
]}

GARIANO, A ^{[1
]}

GUIDA, WC ^{[1
]}

GUIDA, AR ^{[1
]}

HERBST, MD ^{[1
]}

机构：

[1] ECKERD COLL, DEPT CHEM, ST PETERSBURG, FL 33733 USA

来源：

JOURNAL OF ORGANIC CHEMISTRY | 1979年 / 44卷 / 07期

关键词：

D O I：

10.1021/jo01321a027

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The preparation of methyl and ethyl esters of a variety of carboxylic acids using trimethyl- and triethyloxonium tetrafluoroborate has been explored. This method has been found to be successful for a broad series of carboxylic acids including sterically hindered and polyfunctional carboxylic acids. Mild conditions are employed and the reaction is quite rapid in the absence of steric hindrance.Carboxylic acids can be esterified by this procedure in excellent yield to afford products with a high degree of purity. © 1979, American Chemical Society. All rights reserved.

引用

页码：1149 / 1154

页数：6

共 80 条

[71] BASE-CATALYZED PREPARATION OF METHYL + ETHYL ESTERS OF CARBOXYLIC ACIDS [J].