THERMODYNAMICS OF SOLVATION IN MIXED-SOLVENTS

被引:71
作者
WAGHORNE, WE
机构
关键词
D O I
10.1039/cs9932200285
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Chemists have long recognized that changes in solvent have profound effects on the properties of chemical systems. However it is only in the past quarter of a century that theoretical models which will predict these effects have emerged. This article outlines the development of one such model and shows how it provides detailed information about the roles of the interactions between solvent and solute molecules in determining the thermodynamics of chemical systems.
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页码:285 / 292
页数:8
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共 28 条
[21]   SOLUTE SOLVENT INTERACTIONS IN WATER+TERT-BUTYL ALCOHOL MIXTURES .11. ENTHALPIES OF TRANSFER OF AMMONIUM AND TETRA-ALKYLAMMONIUM SALTS [J].
JUILLARD, J .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1982, 78 :37-42
[22]   COMPLEXES OF COPPER(I) AND SILVER(I) WITH ACETONITRILE IN WATER LOWER ALCOHOLS ACETONE AND NITROETHANE [J].
MANAHAN, SE ;
IWAMOTO, RT .
JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1967, 14 (02) :213-&
[23]   PREFERENTIAL SOLVATION OF IONS IN MIXED-SOLVENTS .4. COMPARISON OF THE KIRKWOOD BUFF AND QUASI-LATTICE QUASI-CHEMICAL APPROACHES [J].
MARCUS, Y .
JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1989, 85 :3019-3032
[24]   PARTIAL MOLAL ENTHALPIES, EXCESS PARTIAL MOLAL HEAT CAPACITIES AND STRUCTURAL EFFECTS OF BU4NBR AND NABPH4 IN AQUEOUS BINARY SOLVENT MIXTURES [J].
MOHANTY, RK ;
SARMA, TS ;
SUBRAMAN.S ;
AHLUWALI.JC .
TRANSACTIONS OF THE FARADAY SOCIETY, 1971, 67 (578) :305-&
[25]   THE EFFECTS OF SOLVATION ON THE PROPERTIES OF ANIONS IN DIPOLAR APROTIC SOLVENTS [J].
PARKER, AJ .
QUARTERLY REVIEWS, 1962, 16 (02) :163-187
[26]   EMPIRICAL PARAMETERS OF POLARITY OF SOLVENTS [J].
REICHARDT, C .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1965, 4 (01) :29-+
[27]   UBER AUSWAHLENDE SOLVATATION VON IONEN IN LOSUNGSMITTELGEMISCHEN .4. [J].
SCHNEIDER, H ;
STREHLOW, H .
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1966, 49 (1-2) :44-+
[28]  
SYMONS MCR, 1986, WATER AQUEOUS SOLUTI, P41