FACILE ADDITION OF ALKYNES TO (CPCO)3(CO)2 - GENERAL-METHOD FOR THE SYNTHESIS OF (CPCO)3(CO)(RCCR') COMPLEXES

被引：13

作者：

BARNES, CE

ORVIS, JA

FINNISS, GM

机构：

[1] Department of Chemistry, University of Tennessee, Knoxville

来源：

ORGANOMETALLICS | 1990年 / 9卷 / 05期

关键词：

D O I：

10.1021/om00119a050

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Incorporation of alkynes into the framework of (CpCo)3(CO)2 occurs at room temperature to produce alkyne-carbonyl complexes of the form (CpCo)3(CO)-(RCCR’). The structure of the 3-hexyne adduct is described as well as preliminary observations on the dynamic properties of these complexes. © 1990, American Chemical Society. All rights reserved.

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页码：1695 / 1697

页数：3

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