REGIOCONTROL IN REDUCTIVE RING-OPENING OF EPOXIDES DERIVED FROM ASYMMETRIZED 2-ALKENYL-1,3-PROPANEDIOLS

被引：11

作者：

GUANTI, G ^{[1
]}

BANFI, L ^{[1
]}

MERLO, V ^{[1
]}

NARISANO, E ^{[1
]}

机构：

[1] CNR,CTR STUDIO CHIM COMPOSTI CICLOALIFAT & AROMAT,I-16132 GENOA,ITALY

来源：

TETRAHEDRON | 1994年 / 50卷 / 07期

关键词：

D O I：

10.1016/S0040-4020(01)85080-8

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Homochiral cis epoxides derived from asymmetrized 2-alkenyl-1,3-propanediols are efficiently opened by a variety of hydride donors in the presence of Lewis acids to differently protected triols with a regioselectivity up to 99 : 1.

引用

页码：2219 / 2230

页数：12

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