FAR INFRARED-ABSORPTION IN BULK AMORPHOUS RED PHOSPHORUS

被引:7
作者
SHANABROOK, BV [1 ]
LANNIN, JS [1 ]
TAYLOR, PC [1 ]
机构
[1] USN,RES LAB,WASHINGTON,DC 20375
基金
美国国家科学基金会;
关键词
D O I
10.1016/0038-1098(79)90884-6
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Far infrared absorption measurements have been performed above 30 cm-1 in bulk amorphous red P at 300 K. A number of low frequency spectral features are observed that are not present in the corresponding bulk amorphous As spectrum. Deep minima observed at 163 and 320 cm-1 in α(ω) and in the Raman spectra suggest that the phonon density of states is essentially divided into 3 bands. A calculation of the mean effective charge of the bands indicates weak coupling to the lowest frequency band. A comparison with the results in a-As suggests a less rapid frequency variation in the infrared coupling parameter at low frequencies in a-P. © 1979.
引用
收藏
页码:1279 / 1283
页数:5
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