BISMUTH(III) DIMETHYLDITHIOPHOSPHINATE, BI(S2PME2)3 - ANOTHER DIMER FORMED THROUGH SECONDARY BONDING - THE STEREOCHEMICALLY ACTIVE LONE-PAIR REVISITED

被引：19

作者：

EDELMANN, FT

NOLTEMEYER, M

HAIDUC, I

SILVESTRU, C

CEAOLIVARES, R

机构：

[1] NATL AUTONOMOUS UNIV MEXICO,INST QUIM,CIUDAD UNIV,MEXICO CITY 04510,DF,MEXICO

[2] UNIV GOTTINGEN,INST ANORGAN CHEM,W-3400 GOTTINGEN,GERMANY

来源：

POLYHEDRON | 1994年 / 13卷 / 04期

关键词：

D O I：

10.1016/S0277-5387(00)84730-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The crystal and molecular structures of bismuth(III) dimethyl-dithiophosphinate, Bi(S2PMe2)3 were investigated by X-ray diffraction. The compound is a centrosymmetric dimer in which pentagonal-bipyramidal monomeric units are held together by secondary Bi...S interaction. The possible presence of a stereochemically active lone pair is discussed.

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页码：547 / 552

页数：6

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