STUDIES WITH RADIOACTIVE SUGARS .2. ETHANETHIOLYSIS OF D-XYLOSE

被引：10

作者：

FERRIER, RJ

HATTON, LR

OVEREND, WG

机构：

来源：

CARBOHYDRATE RESEARCH | 1968年 / 6卷 / 01期

关键词：

D O I：

10.1016/S0008-6215(00)80061-0

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

d-Xylose in ethanethiol-N,N-dimethylformamide (4:1), and in the presence of an acid catalyst, reacts to give ethyl thiofuranosides which are then converted chiefly into d-xylose diethyl dithioacetal. This then slowly loses water and unergoes migration of an ethylthio group to give 3-ethylthio-2-(ethylthiomethyl)furan. Pyranosides do not comprise more than 6% of the products of ethanethiolysis at any stage. © 1968.

引用

页码：87 / &

共 31 条

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