STUDIES WITH RADIOACTIVE SUGARS .I. ASPECTS OF ALCOHOLYSIS OF D-XYLOSE AND D-GLUCOSE - ROLE OF ACYCLIC ACETALS

被引：29

作者：

FERRIER, RJ

HATTON, LR

机构：

来源：

CARBOHYDRATE RESEARCH | 1968年 / 6卷 / 01期

关键词：

D O I：

10.1016/S0008-6215(00)80060-9

中图分类号：

Q5 [生物化学]; Q7 [分子生物学];

学科分类号：

071010 ; 081704 ;

摘要：

Examination of the early stages of the acid-catalysed methanolysis of d-xylose and d-glucose, using radioactive sugars, has shown that the hitherto undetected dimethyl acetals are formed, but that they are not primary products, and their concentrations do not exceed 2.5% at any stage. The possible mechanisms of the first step in glycosidation are discussed, and the suggested retention of anomeric configuration occurring during the ring expansion of furanosides is reconsidered. © 1968.

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页码：75 / &

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