THE FIRST TRANSITION-METAL ETA(2)-SIH4 COMPLEXES, CIS-MO(ETA(2)-SIH4)(CO)(R(2)PC(2)H(4)PR(2))(2), AND UNPRECEDENTED TAUTOMERIC EQUILIBRIUM BETWEEN AN ETA(2)-SILANE COMPLEX AND A HYDRIDOSILYL SPECIES - A MODEL FOR METHANE COORDINATION AND ACTIVATION

被引：108

作者：

LUO, XL

KUBAS, GJ

BURNS, CJ

BRYAN, JC

UNKEFER, CJ

机构：

[1] Materials and Chemical Design Group (CST-10), Mail Stop C346, Los Alamos National Laboratory, Los Alamos

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1995年 / 117卷 / 03期

关键词：

D O I：

10.1021/ja00108a045

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[No abstract available]

引用

页码：1159 / 1160

页数：2

共 29 条

[11] ACTIVATION OF METHANE BY IRIDIUM COMPLEXES
HOYANO, JK
MCMASTER, AD
GRAHAM, WAG
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (24) : 7190 - 7191
[12] REACTIONS OF TRANSITION-METAL DIHYDROGEN COMPLEXES
JESSOP, PG
MORRIS, RH
[J]. COORDINATION CHEMISTRY REVIEWS, 1992, 121 : 155 - 284
[13] WIDE-RANGE OF PKA VALUES OF COORDINATED DIHYDROGEN - SYNTHESIS AND PROPERTIES OF SOME ETA-2-DIHYDROGEN AND DIHYDRIDE COMPLEXES OF RUTHENIUM
JIA, G
MORRIS, RH
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (03) : 875 - 883
[14] MOLECULAR-HYDROGEN COMPLEXES OF THE TRANSITION-METALS .4. PREPARATION AND CHARACTERIZATION OF MO(CO)3(PR3)2(ETA-2-H-2), W(CO)3(PR3)2(ETA-2-H-2) AND EVIDENCE FOR EQUILIBRIUM DISSOCIATION OF THE H-H BOND TO GIVE MH2(CO)3(PR3)2
KUBAS, GJ
UNKEFER, CJ
SWANSON, BI
FUKUSHIMA, E
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1986, 108 (22) : 7000 - 7009
[15] MOLECULAR-HYDROGEN COMPLEXES - COORDINATION OF A SIGMA-BOND TO TRANSITION-METALS
KUBAS, GJ
[J]. ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (03) : 120 - 128
[16] MOLECULAR-HYDROGEN COMPLEXES .5. ELECTRONIC CONTROL OF ETA2-H2 VERSUS DIHYDRIDE COORDINATION - DIHYDRIDE STRUCTURE OF MOH2(CO)(R2PC2H4PR2)2 FOR R = ET, I-BU VERSUS ETA2-H2 FOR R = PH
KUBAS, GJ
RYAN, RR
UNKEFER, CJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1987, 109 (26) : 8113 - 8115
[17] NEUTRON STRUCTURE AND INELASTIC-NEUTRON-SCATTERING AND THEORETICAL-STUDIES OF MO(CO)(H2)[(C6D5)2PC2H4P(C6D5)2]2.4.5C6D6, A COMPLEX WITH AN EXTREMELY LOW BARRIER TO H-2 ROTATION - IMPLICATIONS ON THE REACTION COORDINATE FOR H-H CLEAVAGE TO DIHYDRIDE
KUBAS, GJ
BURNS, CJ
ECKERT, J
JOHNSON, SW
LARSON, AC
VERGAMINI, PJ
UNKEFER, CJ
KHALSA, GRK
JACKSON, SA
EISENSTEIN, O
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (02) : 569 - 581
[18] UNUSUAL FLUXIONAL AND T1 PROPERTIES FOR [REH4(CO)(PME2PH)3]+ - A POLYHYDRIDE WITH CLASSICAL AND NONCLASSICAL TAUTOMERS
LUO, XL
CRABTREE, RH
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1990, (02) : 189 - 190
[19] SYNTHESIS AND CHARACTERIZATION OF MOLYBDENUM COMPLEXES CONTAINING DIPHOSPHINE LIGANDS OF THE TYPE (ARCH2)(2)PC2H4P(CH2AR)(2)(AR=C(6)H(4)X) - ELECTRONIC CONTROL OF ETA(2)-DIHYDROGEN VERSUS DIHYDRIDE COORDINATION IN MOH2(CO)((RCH(2))(2)PC2H4P(CH(2)R)(2))(2) (R= ME, PR-I, C(6)H(4)X) AND IMPLICATIONS ON THE REACTION COORDINATE FOR H-2 CLEAVAGE
LUO, XL
KUBAS, GJ
BURNS, CJ
ECKERT, J
[J]. INORGANIC CHEMISTRY, 1994, 33 (23) : 5219 - 5229
[20] ETA(2)-COORDINATION OF SI-H SIGMA-BONDS TO TRANSITION-METAL FRAGMENTS THAT ALSO BIND ETA(2)-DIHYDROGEN LIGANDS AND AGOSTIC C-H BONDS - SYNTHESIS AND CHARACTERIZATION OF ETA(2)-SILANE COMPLEXES CIS-MO(ETA(2)-H-SIHR'(2))(CO)(R(2)PC(2)H(4)PR(2))(2)
LUO, XL
KUBAS, GJ
BRYAN, JC
BURNS, CJ
UNKEFER, CJ
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (22) : 10312 - 10313

← 1 2 3 →