ABSOLUTE INTENSITY OF THIN-FILM C6H6(S) FROM REFLECTANCE AND TRANSMITTANCE NEAR 680 CM-1

被引：3

作者：

GLOVER, DE

HOLLENBERG, JL

机构：

[1] Department of Chemistry, University of Redlands, Redlands

来源：

JOURNAL OF PHYSICAL CHEMISTRY | 1969年 / 73卷 / 04期

关键词：

D O I：

10.1021/j100724a022

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The infrared reflectance and transmittance spectra of the ν11 (a2u) fundamental of C6H6(s) for thin films have been measured. Optical expressions for the reflectance and transmittance of thin films have been used to calculate the refractive index n and the absorption index k. Integration of k over the band gives an absolute intensity Γ = 11.7 ± 1.3 cm2 mmol-1, which is about 36% lower than the apparent absorption intensity of 15.9. Comparison to results of other workers is made.

引用

页码：889 / +

页数：1

共 15 条

[1] PRECISION MEASUREMENT OF ABSOLUTE SPECULAR REFLECTANCE WITH MINIMIZED SYSTEMATIC ERRORS [J].