AROMATIC SUBSTITUTION OF OLEFINS .6. ARYLATION OF OLEFINS WITH PALLADIUM(II) ACETATE

被引：509

作者：

FUJIWARA, Y

MORITANI, I

DANNO, S

ASANO, R

TERANISH.S

机构：

[1] Department of Chemistry, Osaka University at Machikaneyama, Toyonaka, Osaka

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 1969年 / 91卷 / 25期

关键词：

D O I：

10.1021/ja01053a047

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Olefins react with benzene derivatives to produce aryl-substituted olefins via direct substitution of the aromatic compound for hydrogen on the double bond of the olefin in the presence of palladium salts and reduced palladium metal. The reaction may be made catalytic with respect to the palladium salts by using cupric acetate or silver acetate, and air as reoxidants. The reaction provides an extremely convenient method for the synthesis of a wide variety of olefimc compounds. © 1969, American Chemical Society. All rights reserved.

引用

页码：7166 / &

共 25 条

[1]

AGUILO A, 1967, ADV ORGANOMET CHEM, V5, P321

[2] THE RELATIVE AFFINITIES OF LIGAND ATOMS FOR ACCEPTOR MOLECULES AND IONS [J].