ZEOLITE-ENCAPSULATED AND CLAY-INTERCALATED METAL PORPHYRIN, PHTHALOCYANINE AND SCHIFF-BASE COMPLEXES AS MODELS FOR BIOMIMETIC OXIDATION CATALYSTS - AN OVERVIEW

被引：418

作者：

BEDIOUI, F

机构：

[1] Laboratoire d'Electrochimie et de Chimie Analytique (URA no. 216 du CNRS), Ecole Nationale Supérieure de Chimie de Paris, 75231 Paris Cedex 05

来源：

COORDINATION CHEMISTRY REVIEWS | 1995年 / 144卷

关键词：

CLAYS; ZEOLITES; BIOMIMETIC OXIDATION CATALYSTS; SCHIFF BASES; PORPHYRINS; PHTHALOCYANINES;

D O I：

10.1016/0010-8545(94)08000-H

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This paper reviews some important recent work on the design and characterization of zeolite-encapsulated and clay-intercalated metal-Schiff-base, -porphyrin and -phthalocyanine complexes. After an introduction to the chemistry of clays and zeolites, the incorporation methods of these complexes within the mineral materials are discussed and an overview of their physicochemical characterization is reported. A large part of this paper is devoted to the reactivity of the zeolite- and clay-encapsulated complexes in biomimetic oxidation reactions.

引用

页码：39 / 68

页数：30

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