SPATIAL-DISPERSION OF ELECTRON-TRANSFER PROBABILITY

被引：37

作者：

BURSHTEIN, AI

FRANTSUZOV, PA

ZHARIKOV, AA

机构：

[1] Institute of Chemical Kinetics and Combustion

来源：

CHEMICAL PHYSICS | 1991年 / 155卷 / 01期

关键词：

D O I：

10.1016/0301-0104(91)87009-K

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Recombination and ionization rate constants were calculated taking into account the spatial dispersion of reaction free and reorganization energies. The conditions were found under which the reactions are contact and the contact estimation of their rate is invalid. The spatial dispersion of transfer probability was shown to be responsible for the smoothing of the multichannel structure of the free energy "gap" dependence of the rate constant.

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页码：91 / 98

页数：8

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